I just checked out your logs: it looks like there may be permission issues or something else funky going on with your /ps/tmp bind mount: SQLite isn’t able to successfully set up your library database, so you’re seeing this error (this is from running logcat on the zipfile you sent me, btw):
If your library is stored on a drive within your NAS, I’d set the environment variable PS_FORCE_LOCAL_DB_REPLICA=false in your docker config and restart. There’s more details about this issue here: What's PS_FORCE_LOCAL_DB_REPLICA?